This advice is already all over this board but:
Make sure your car has good winter tyres. If it snows or is cold and you're on small narrow/twisty mountain roads be careful, don't drive like the Austrians do. Make sure you have high viz vests and all the other guff the Austrians require of you.
You don't need to go far to see nice things, but before going for a walk I'd get a guide book. Search this board for
Michael Pause for a book I like (in German but you'll get the idea). A great walk is from Walchensee up the cable car to Heimgarten.
For driving tours the 305 towards Salzburg is quite OK round the edge of the mountains.
Overnight stays are fun and usually it's not necessary to book as you'll always find something if you're a bit creative (many towns have a directory of hotels on the main road into the town with a free phone) unless this happens to be a big school holiday weekend.
Maybe you could give some more clues as to what you would like to do?